Chapter 8 Covalent Bonding Section 8.1 Molecular Compounds OBJECTIVES: Distinguish between the melting points and
boiling points of molecular compounds and ionic compounds. Section 8.1 Molecular Compounds OBJECTIVES: Describe the information provided by a molecular formula.
Bonds Forces that hold groups of atoms together and make them function as a unit: 1) Ionic bonds transfer of electrons (gained or lost) 2) Covalent bonds sharing of electrons. The resulting particle is called a molecule.
Molecules Many elements found in nature are in the form of molecules: a neutral group of atoms joined together by covalent bonds. For example, air contains oxygen
molecules, consisting of two oxygen atoms joined covalently Called a diatomic molecule How does H2 form? The nuclei repel each other, since they both have a positive charge, and like charges repel. + +
How does H2 form? But, the nuclei are attracted to the electrons They share the electrons, and this is called a covalent bond, and involves only NONMETALS! + + Covalent bonds
Nonmetals hold on to their valence electrons. They cant give away electrons to bond. Still want noble gas configuration. Get it by sharing valence electrons with each other = covalent bonding
By sharing, both atoms get to count the electrons toward a noble gas configuration. Covalent bonding Fluorine has seven valence electrons F Covalent bonding Fluorine has seven valence
electrons A second atom also has seven F F Covalent bonding Fluorine has seven valence electrons
A second atom also has seven By sharing electrons F F Covalent bonding Fluorine has seven valence electrons A second atom also has seven By sharing electrons
F F Covalent bonding Fluorine has seven valence electrons A second atom also has seven By sharing electrons F F
Covalent bonding Fluorine has seven valence electrons A second atom also has seven By sharing electrons F F Covalent bonding Fluorine
has seven valence electrons A second atom also has seven By sharing electrons F F Covalent bonding Fluorine has seven valence electrons A second atom also has seven By sharing electrons both
end with full orbitals F F Covalent bonding Fluorine has seven valence electrons A second atom also has seven By sharing electrons both end with full orbitals F F
8 Valence electrons Covalent bonding Fluorine has seven valence electrons A second atom also has seven By sharing electrons both end with full orbitals 8 Valence electrons F F
Molecular Compounds Compounds that are bonded covalently (like water and carbon dioxide) are called molecular compounds Molecular compounds tend to have relatively lower melting and boiling points than ionic compounds. Molecular Compounds
Thus, molecular compounds tend to be gases or liquids at room temperature Ionic compounds were solids A molecular compound consists of a molecular formula: Shows how many atoms of each element a molecule contains Molecular Compounds The formula for water is written as H2 O
The subscript 2 behind hydrogen means there are 2 atoms of hydrogen; if there is only one atom, the subscript 1 is omitted Molecular formulas do not tell any information about the structure (the arrangement of the various atoms). - Page 215 These are some of the different ways to represent ammonia:
1. The molecular formula shows how many atoms of each element are present 2. The structural formula ALSO shows the arrangement of these atoms! 3. The ball and stick model is the BEST, because it shows
a 3-dimensional arrangement. Section 8.2 The Nature of Covalent Bonding OBJECTIVES: Describe how electrons are shared to form covalent bonds, and identify exceptions to the octet rule.
Section 8.2 The Nature of Covalent Bonding OBJECTIVES: Demonstrate how electron dot structures represent shared electrons. Section 8.2
The Nature of Covalent Bonding OBJECTIVES: Describe how atoms form double or triple covalent bonds. Section 8.2 The Nature of Covalent Bonding
OBJECTIVES: Distinguish between a covalent bond and a coordinate covalent bond, and describe how the strength of a covalent bond is related to its bond dissociation energy. Section 8.2 The Nature of Covalent Bonding
OBJECTIVES: Describe how oxygen atoms are bonded in ozone. A Single Covalent Bond is... A sharing of two valence electrons. Only nonmetals and hydrogen. Different from an ionic bond because
they actually form molecules. Two specific atoms are joined. In an ionic solid, you cant tell which atom the electrons moved from or to Sodium Chloride Crystal Lattice Ionic compounds organize in a characteristic crystal lattice of alternating
positive and negative ions. How to show the formation Its like a jigsaw puzzle. You put the pieces together to end up with the right formula. Carbon is a special example - can it really share 4 electrons: 1s22s22p2?
Yes, due to electron promotion! Another example: lets show how water is formed with covalent bonds, by using an electron dot diagram Water H O
Each hydrogen has 1 valence electron Each hydrogen wants 1 more The oxygen has 6 valence electrons The oxygen wants 2 more They share to make each other complete Water Put the pieces together
The first hydrogen is happy The oxygen still wants one more HO Water A second hydrogen attaches Every atom has full energy levels HO
H Note the two unshared pairs of electrons Multiple Bonds Sometimes atoms share more than one pair of valence electrons. A double bond is when atoms share two pairs of electrons (4 total) A triple bond is when atoms share
three pairs of electrons (6 total) Table 8.1, p.222 - Know these 7 elements as diatomic: Whats the deal with the oxygen Br2 I2 N2 Cl2 H2 O2 F2 dot diagram? Dot diagram for Carbon dioxide C
O CO2 - Carbon is central atom ( more metallic ) Carbon has 4 valence electrons Wants 4 more Oxygen has 6 valence electrons Wants 2 more
Carbon dioxide Attaching 1 oxygen leaves the oxygen 1 short, and the carbon 3 short CO Carbon dioxide Attaching
the second oxygen leaves both oxygen 1 short, and the carbon 2 short OC O Carbon dioxide The only solution is to share more O CO Carbon dioxide
The only solution is to share more O CO Carbon dioxide The only solution is to share more O CO Carbon dioxide
The only solution is to share more O C O Carbon dioxide The only solution is to share more O C O Carbon dioxide
The only solution is to share more O C O Carbon dioxide The only solution is to share more Requires two double bonds Each atom can count all the electrons in the bond
O C O Carbon dioxide The only solution is to share more Requires two double bonds Each atom can count all the electrons in the bond 8 valence electrons O C O Carbon dioxide
The only solution is to share more Requires two double bonds Each atom can count all the electrons in the bond 8 valence electrons O C O Carbon dioxide The only solution is to share more Requires two double bonds Each atom can count all the electrons in
the bond 8 valence electrons O C O How to draw them? Use the handout guidelines: Add up all the valence electrons. Count up the total number of electrons to make all atoms happy.
Subtract; then Divide by 2 Tells you how many bonds to draw Fill in the rest of the valence electrons to fill atoms up. Example N H
NH3, which is ammonia N central atom; has 5 valence electrons, wants 8 H - has 1 (x3) valence
electrons, wants 2 (x3) NH3 has 5+3 = 8 NH3 wants 8+6 = 14 (14-8)/2= 3 bonds 4 atoms with 3 bonds Examples Draw in the bonds; start with singles All 8 electrons are accounted for Everything is full done with this one.
H H NH Example: HCN
HCN: C is central atom N - has 5 valence electrons, wants 8 C - has 4 valence electrons, wants 8 H - has 1 valence electron, wants 2 HCN has 5+4+1 = 10 HCN wants 8+8+2 = 18 (18-10)/2= 4 bonds 3 atoms with 4 bonds this will require multiple bonds - not to H however HCN
Put single bond between each atom Need to add 2 more bonds Must go between C and N (Hydrogen is full) HC N HCN Put in single bonds Needs 2 more bonds Must go between C and N, not the H Uses 8 electrons need 2 more to
equal the 10 it has HC N HCN Put in single bonds Need 2 more bonds Must go between C and N Uses 8 electrons - 2 more to add Must go on the N to fill its octet HC N
Another way of indicating bonds Often use a line to indicate a bond Called a structural formula Each line is 2 valence electrons HOH H O H = Other Structural Examples
H C N H C O H A Coordinate Covalent Bond... When one atom donates both electrons in a covalent bond. Carbon monoxide (CO) is a good example:
Both the carbon and oxygen give another single electron to share CO Coordinate Covalent Bond When one atom donates both electrons in a covalent bond. Carbon monoxide (CO) is a good Oxygen
example: This carbon electron moves to make a pair with the other single. C O gives both of these electrons, since it has
no more singles to share. Coordinate Covalent Bond When one atom donates both electrons in a covalent bond. Carbon monoxide (CO) The coordinate covalent bond is shown with
an arrow as: C O C O Coordinate covalent bond Most polyatomic cations and anions contain covalent and coordinate covalent bonds Table 8.2, p.224
Sample Problem 8.2, p.225 The ammonium ion can be shown as another example Bond Dissociation Energies... The total energy required to break the bond between 2 covalently bonded atoms High dissociation energy usually means the chemical is relatively
unreactive, because it takes a lot of energy to break it down. Resonance is... When more than one valid dot diagram is possible. Consider the two ways to draw ozone (O3)
Which one is it? Does it go back and forth? It is a hybrid of both, like a mule; and shown by a double-headed arrow found in double bond structures Resonance in Ozone Note the different location of the double bond Neither structure is correct, it is
actually a hybrid of the two. To show it, draw all varieties possible, and join them with a double-headed arrow. Resonance Occurs when more than one valid Lewis structure can be written for a particular molecule (due to position of double bond) These are resonance structures of benzene. The actual structure is an average (or hybrid) of these structures. Polyatomic ions note the different
positions of the double bond. Resonance in a carbonate ion: Resonance in an acetate ion: Exceptions to Octet rule For some molecules, it is impossible to satisfy the octet rule usually when there is an odd
number of valence electrons NO2 has 17 valence electrons, because the N has 5, and each O contributes 6 It is impossible to satisfy octet rule, yet the stable molecule does exist Exceptions to Octet rule
Another exception: Boron Page 228 shows boron trifluoride, and note that one of the fluorides might be able to make a coordinate covalent bond to fulfill the boron But fluorine has the highest electronegativity of any element, so this coordinate bond does not form Top page 229 examples exist because they are in period 3 or beyond Section 8.3 Bonding Theories
OBJECTIVES: Describe the relationship between atomic and molecular orbitals. Section 8.3 Bonding Theories OBJECTIVES: Describe
how VSEPR theory helps predict the shapes of molecules. Molecular Orbitals are... The model for covalent bonding assumes the orbitals are those of the individual atoms = atomic orbital Orbitals that apply to the overall molecule, due to atomic orbital overlap are the molecular orbitals A bonding orbital is a molecular
orbital that can be occupied by two electrons of a covalent bond Molecular Orbitals Sigma bond- when two atomic orbitals combine to form the molecular orbital that is symmetrical along the axis connecting the nuclei Pi bond- the bonding electrons are likely to be found above and below the bond axis (weaker than sigma)
Note pictures on the next slide - Pages 230 and 231 Sigma bond is symmetrical along the axis between the two nuclei. Pi bond is above and below the bond axis, and is weaker
than sigma VSEPR: stands for... Valence Shell Electron Pair Repulsion Predicts the three dimensional shape of molecules. The name tells you the theory:
Valence shell = outside electrons. Electron Pair repulsion - electron pairs try to get as far away as possible from each other. Can determine the angles of bonds. VSEPR Based on the number of pairs of valence electrons both bonded and unbonded. Unbonded pair also called lone pair. CH4 - draw the structural formula
Has 4 + 4(1) = 8 wants 8 + 4(2) = 16 (16-8)/2 = 4 bonds VSEPR for methane: Single bonds fill all atoms.
There are 4 pairs of electrons pushing away. The furthest they can get away is 109.5 H H C H H
4 atoms bonded Basic shape is tetrahedral. A pyramid with a triangular base. Same shape for everything with
4 pairs. H H C H 109.5 H Other angles, pages 232 - 233
Ammonia (NH3) = 107o Water (H2O) = 105o Carbon dioxide (CO2) = 180o Note the shapes of these that are pictured on the next slide - Page 232 Methane has an angle of 109.5o, called
tetrahedral Ammonia has an angle of 107o, called pyramidal Note the unshared pair that is repulsion for other electrons. Section 8.4 Polar Bonds and Molecules OBJECTIVES: Describe how
electronegativity values determine the distribution of charge in a polar molecule. Section 8.4 Polar Bonds and Molecules OBJECTIVES: Describe what happens to polar molecules when
they are placed between oppositely charged metal plates. Section 8.4 Polar Bonds and Molecules OBJECTIVES: Evaluate the strength of intermolecular attractions compared
with the strength of ionic and covalent bonds. Section 8.4 Polar Bonds and Molecules OBJECTIVES: Identify the reason why network solids have high melting points.
Bond Polarity Covalent bonding means shared electrons but, do they share equally? Electrons are pulled, as in a tug-ofwar, between the atoms nuclei In equal sharing (such as diatomic molecules), the bond that results is called a nonpolar covalent bond Bond Polarity
When two different atoms bond covalently, there is an unequal sharing the more electronegative atom will have a stronger attraction, and will acquire a slightly negative charge called a polar covalent bond, or simply polar bond. Electronegativity The ability of an atom in a molecule to attract shared
electrons to itself. Linus Pauling 1901 - 1994 Table of Electronegativities Bond Polarity Refer to Table 6.2, page 177 Consider HCl H = electronegativity of 2.1 Cl = electronegativity of 3.0 the bond is polar
the chlorine acquires a slight negative charge, and the hydrogen a slight positive charge Bond Polarity Only partial charges, much less than a true 1+ or 1- as in ionic bond Written as:
H Cl the positive and minus signs (with the lower case delta: and ) denote partial charges. Bond Polarity
Can also be shown: H Cl the arrow points to the more electronegative atom. Table 8.3, p.238 shows how the electronegativity can also indicate the type of bond that tends to form Polar molecules Sample Problem 8.3, p.239 A polar bond tends to make the
entire molecule polar areas of difference HCl has polar bonds, thus is a polar molecule. A molecule that has two poles is called dipole, like HCl Polar molecules The effect of polar bonds on the polarity of the entire molecule
depends on the molecule shape carbon dioxide has two polar bonds, and is linear = nonpolar molecule! Polar molecules The effect of polar bonds on the polarity of the entire molecule depends on the molecule shape water has two polar bonds and a bent shape;
the highly electronegative oxygen pulls the e away from H = very polar! Polar molecules When polar molecules are placed between oppositely charged plates, they tend to become oriented with respect to the positive and negative plates. Figure 8.24, page 239
Attractions between They are whatmolecules make solid and liquid molecular compounds possible. The weakest are called van der Waals forces - there are two kinds: 1. Dispersion forces weakest of all, caused by motion of eincreases as # e- increases halogens start as gases; bromine is liquid; iodine is solid all in Group 7A 2. Dipole interactions
Occurs when polar molecules are attracted to each other. 2. Dipole interaction happens in water Figure 8.25, page 240 positive region of one molecule attracts the negative region of another molecule. 2. Dipole interactions
Occur when polar molecules are attracted to each other. Slightly stronger than dispersion forces. Opposites attract, but not completely hooked like in ionic solids. H F H F
2. Dipole Interactions
3. Hydrogen bonding? is the attractive force caused by hydrogen bonded to N, O, F, or Cl N, O, F, and Cl are very electronegative, so this is a very strong dipole. The hydrogen partially share with the lone pair in the molecule next to it. This is the strongest of the
intermolecular forces. 3. Hydrogen bonding defined: When a hydrogen atom is: a) covalently bonded to a highly electronegative atom, AND b) is also weakly bonded to an unshared electron pair of a nearby highly electronegative atom. The hydrogen is left very electron deficient, thus it shares with something nearby
Hydrogen is also the ONLY element with no shielding for its nucleus when involved in a covalent bond! Hydrogen Bonding - + + H O H + H
O + H H H O
H H H O H H H H O
H O H H O O H O H Hydrogen bonding Attractions and properties
Why are some chemicals gases, some liquids, some solids? Depends on the type of bonding! Table 8.4, page 244 Network solids solids in which all the atoms are covalently bonded to each other Attractions and properties Figure 8.28, page 243
melts at very high temperatures, or not at all Diamond does not really melt, but vaporizes to a gas at 3500 oC and beyond SiC, used in grinding, has a melting point of about 2700 oC Covalent Network Compounds Some covalently bonded substances DO NOT form discrete molecules.
Diamond, a network of covalently bonded carbon atoms Graphite, a network of covalently bonded carbon atoms
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